Journal of Siberian Federal University. Chemistry / The Sodium Alcoholate/Alcohol/DMSO System in the Reaction of Cyanoacetic Ether with Alkyl Azides

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2026 19 (3)
Authors
Strokova, Svetlana V.; Shumilova, Elena Yu.; Lenskiy, Maksim A.; Sysolyatin, Sergey V.
Contact information
Strokova, Svetlana V.: Institute for Problems of Chemical and Energetic Technologies SB RAS (Biysk, Russian Federation); ; Shumilova, Elena Yu. : Institute for Problems of Chemical and Energetic Technologies SB RAS (Biysk, Russian Federation); Lenskiy, Maksim A. : Institute for Problems of Chemical and Energetic Technologies SB RAS (Biysk, Russian Federation); Sysolyatin, Sergey V.: Institute for Problems of Chemical and Energetic Technologies SB RAS (Biysk, Russian Federation)
Keywords
5-amino-1,2,3-triazoles; cyanoacetic ether; benzyl azide; DMSO
Abstract

The sodium alcoholate/alcohol/DMSO system made it possible to obtain 5-amino-1-benzyl-1,2,3- triazole‑4‑carboxylates with high yields and with a purity of raw materials above 95 % (HPLC) by reaction of benzyl azide with cyanoacetic ether. These conditions are more effective than those previously described. It is shown that the developed system is too aggressive for 2‑(azidomethyl)‑1H‑benzoimidazole and 2-azidoacetamide

Pages
528–535
EDN
MZLKGS
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/160141