Journal of Siberian Federal University. Chemistry / Redox Properties of Mononuclear Dicarbonyl and Carbonylphosphine Rhodium (I) Complexes Containing β-diketonate Ligands

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2019 12 (3)
Authors
Burmakina, Galina V.; Verpekin, Victor V.; Zimonin, Dmitry V.; Chudin, Oleg S.; Nedelina, Tatyana S.; Rubaylo, Anatoly I.
Contact information
Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; , ; Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Nedelina, Tatyana S.: Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
redox properties; electrochemistry; rhodium; carbonyl; carbonylphosphine; β-diketonate ligands
Abstract

The redox properties of mononuclear dicarbonyl and carbonylphosphine rhodium (I) complexes (CO)(L)Rh(RC(O)CHC(O)R’) with chelate β-diketonate ligands (L = CO, PPh3; R, R’ = Me, Ph; CF3, C4H3S) were studied by electrochemical methods at platinum, glassed carbon and dropping mercury electrodes in acetonitrile. Schemes of their redox reactions were established

Pages
413-422
DOI
10.17516/1998-2836-0138
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/125627