Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2009 2 (1)
- Authors
- Chaenko, Natalya V.; Kornienko, Vasily L.; Kornienko, Galina V.
- Contact information
- Chaenko, Natalya V. 42 K. Marx st., Krasnoyarsk, 660049 Russia 79 Svobodny, Krasnoyarsk, 660041 Russia ; Kornienko, Vasily L. 42 K. Marx st., Krasnoyarsk, 660049 Russia; Kornienko, Galina V. 42 K. Marx st., Krasnoyarsk, 660049 Russia
- Keywords
- Oxidation; redox-mediators; aliphatic alcohols; nickel hydroxide; porous hydrophobized anodes; carboxylic acids; cobalt oxide
- Abstract
Redox-mediator oxidation of aliphatic alcohols to carboxylic acids on nickel hydroxide (ONE) and cobalt oxide (OCE) porous hydrophobized electrodes in alkaline medium was studied. A method of producing porous hydrophobized nickel hydroxide electrodes developed. Kinetics and selectivity of the indirect oxidation of isobutyl, isoamyl, hexyl , nonanoic and undecenol alcohols to the corresponding carboxylic acids are studied. Studies have shown the efficiency of application of porous hydrophobized oxide-nickel electrodes for redox-mediator oxidation of aliphatic alcohols with long carbon chain C6 - C9 in the potential window 0.7 -0.9 V(vs. SCE).
- Pages
- 64-70
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/1307
Journal of Siberian Federal University. Chemistry / Redox-Mediator Oxidation of Aliphatic Alcohols to Carboxylic Acids on Nickel Hydroxide and Cobaltoxide Porous Hydrophobized Electrodes
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