Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2009 2 (1)
- Authors
- Shestopalov, Michael A.; Kozhomuratova, Zhyldyz S.; Smolentsev, Anton I.; Mironov, Yuri V.; Perrin, André; Perrin, Christiane; Fedorov, Vladimir E.
- Contact information
- Shestopalov, Michael A. 3 Acad. Lavrentiev, Novosibirsk, 630090 Russia; Kozhomuratova, Zhyldyz S. 3 Acad. Lavrentiev, Novosibirsk, 630090 Russia; Smolentsev, Anton I. 3 Acad. Lavrentiev, Novosibirsk, 630090 Russia; Mironov, Yuri V. 3 Acad. Lavrentiev, Novosibirsk, 630090 Russia; Perrin, André Avenue du Général Leclerc, 35042 Rennes Cedex, France; Perrin, Christiane Avenue du Général Leclerc, 35042 Rennes Cedex, France; Fedorov, Vladimir E. 3 Acad. Lavrentiev, Novosibirsk, 630090 Russia
- Keywords
- rhenium; octahedral cluster; triphenylphosphine oxide; synthesis; crystal structure
- Abstract
New cluster complex [cis-Ca(OPPh3)4(H2O)2][{Re6(μ3-S)6(μ3-Br)2}Br6]·2CH3CN was synthesized and structurally characterized. The compound crystallizes in monoclinic C2/c space group with cell parameters: a = 23,0374(6), b = 16,3791(4), c = 25,3383(7) Å, β = 108,924(1)˚, V = 9044,2(4) Å3, Z = 4, ρcalc = 2,365 g/cm3. The compound has ionic structure in which [cis-Ca(OPPh3)4(H2O)2]2+ cations and [{Re6(μ3-S)6(μ3-Br)2}Br6]2- cluster anions interact through hydrogen bonds O-H…Br. In the crystal structure of the compound there are hydrogen bonds O-H…N and π-π stacking interactions between phenyl rings of triphenylphosphine oxide (OPPh3).
- Pages
- 81-88
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/1308
Journal of Siberian Federal University. Chemistry / Structure of the New Octahedral Rhenium Cluster Complexes - [cis-Ca(OPPh3)4(H2O)2][{Re6(μ3-S)6(μ3-Br)2}Br6]·2CH3CN
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