Journal of Siberian Federal University. Chemistry: A Novel Vanadium Catalyst for Oxidation of Hydrogen Chloride with Dioxygen

Journal of Siberian Federal University. Chemistry / A Novel Vanadium Catalyst for Oxidation of Hydrogen Chloride with Dioxygen

Issue: Journal of Siberian Federal University. Chemistry. 2009 2 (1)
Authors: Tarabanko, Valeri E.; Tarabanko, Nikolay V; Zhyzhaev, Anatoly M.; Koropachinskaya, Nataliya V.
Contact information: Tarabanko, Valeri E. 42 K. Marksa st., Krasnoyarsk, 660049 Russia ; Tarabanko, Nikolay V 42 K. Marksa st., Krasnoyarsk, 660049 Russia; Zhyzhaev, Anatoly M. 42 K. Marksa st., Krasnoyarsk, 660049 Russia; Koropachinskaya, Nataliya V. 42 K. Marksa st., Krasnoyarsk, 660049 Russia
Keywords: hydrogen chloride; oxidation; chlorine; oxygen; vanadium; catalyst
Abstract: A novel catalytic system for oxidation of hydrogen chloride, V2O5-LiCl-KCl, has been studied. This catalyst shows activity in a range of relatively low temperatures, 250 - 350 °C. Chlorine yield attains 200 - 780 g per kg of catalyst per hour at 350 °C, which greatly exceeds the characteristics of known vanadium, copper and chromia catalysts.
Pages: 11-18
Paper at repository of SibFU: https://elib.sfu-kras.ru/handle/2311/1309