Journal of Siberian Federal University. Chemistry / Pd/Cu-Catalyzed Coupling of Cyclopentadienyliron Dicarbonyl Iodide and Methyl Propiolate in Synthesis of Cp(CO)₂Fe-C≡C-COOMe

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2020 13 (2)
Authors
Verpekin, Victor V.; Kondrasenko, Alexander A.
Contact information
Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; , ; Kondrasenko, Alexander A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation
Keywords
iron; palladium; copper; iron-carbon coupling; acetylide complexes
Abstract

The conditions of successful iron-carbon coupling in the reaction between cyclopentadienyliron dicarbonyl iodide and methyl propiolate upon the Pd/Cu catalysis were determined. A new high-yield synthetic approach to the methoxycarbonylethynyl iron complex Cp(CO)₂Fe-C≡C-COOMe were developed

Pages
297-303
DOI
10.17516/1998-2836-0183
Paper at repository of SibFU
http://elib.sfu-kras.ru/handle/2311/135406