Journal of Siberian Federal University. Chemistry / Phenylvinylidene RePt Complexes Containing Diphenylphosphine Ligands at the Platinum Atom: Synthesis, IR, NMR Spectroscopic and Electrochemical Properties

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2020 13 (3)
Authors
Chudin, Oleg S.; Verpekin, Victor V.; Burmakina, Galina V.; Zimonin, Dmitry V.; Kondrasenko, Alexander A.; Rubaylo, Anatoly I.
Contact information
Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; , ; Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Kondrasenko, Alexander A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Science Center SB RAS» Krasnoyarsk, Russian Federation
Keywords
electrochemistry; redox properties; binuclear complexes; phenylvinylidene; rhenium; platinum; carbonyl; diphenylphosphine
Abstract

The μ-phenylvinylidene complexes Cp(CO)2RePt(μ-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)3 (2)] were synthesized for the first time. Their IR, NMR spectroscopic and redox properties were studied. Based on IR, NMR spectroscopic data their molecular structures were proposed. The pathways of redox-reactions of the complexes were determined

Pages
385-394
DOI
10.17516/1998-2836-0191
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/136701