Journal of Siberian Federal University. Chemistry / The New μ-Phenylvinylidene RePt Complexes Containing Platinum-Bound 1-(Isocyanomethylsulfonyl)- 4-Methylbenzene

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2020 13 (4)
Authors
Chudin, Oleg S.; Verpekin, Victor V.; Kondrasenko, Alexander A.; Burmakina, Galina V.; Zimonin, Dmitry V.; Korolkova, Irina V.; Rubaylo, Anatoly I.
Contact information
Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; , ; Kondrasenko, Alexander A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russin Federation; Korolkova, Irina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Science Center SB RAS» Krasnoyarsk, Russian Federation
Keywords
rhenium; platinum; vinylidene complexes; heterometallic complexes; carbonyl; isocyanide; electrochemistry
Abstract

The binuclear μ-vinylidene complexes containing an isocyanide ligand (1-(isocyanomethylsulfonyl)-4-methylbenzene) Cp(CO)2RePt(μ-C=CHPh)(TosMIC)(L) [L = PPh3 (1), P(OPri)3 (2)] were synthesized for the first time. The approach afforded 1 and 2 based on the substitution reactions of a platinum bound carbonyl group in Cp(CO)2RePt(μ-C=CHPh)(CO)(L) [L = PPh3 (1a), P(OPri)3 (2a)] upon addition of 1-(isocyanomethylsulfonyl)-4-methylbenzene. The complexes 1 and 2 were characterized by IR and NMR spectroscopy. Their redox properties were studied

Pages
489–498
DOI
10.17516/1998-2836-0200
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/137873