Journal of Siberian Federal University. Chemistry / Electrochemical Study of the Redox Properties of Levulinic Acid in Organic and Aqueous-Organic Solutions

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2021 14 (3)
Authors
Burmakina, Galina V.; Zimonin, Dmitry V.; Rubaylo, Anatoly I.
Contact information
Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS Krasnoyarsk, Russian Federation; , ; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation
Keywords
electrochemistry; redox properties; levulinic acid; γ-valerolactone
Abstract

The redox properties of levulinic acid (LA) were studied by electrochemical methods in acetonitrile, a mixture of acetonitrile with water, ethanol, acetone, and dimethyl sulfoxide. It was shown that the irreversible two-electron reduction of LA under the studied conditions leads to the formation of γ-valerolactone. This reduction potential depends on the solvent and shifted anodically by following order: dimethyl sulfoxide

Pages
388–395
DOI
10.17516/1998-2836-0246
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/144189