Journal of Siberian Federal University. Chemistry / Catalytic oxidation of Cedar Bark (Pinus Sibirica) with Oxygen to Vanillin and Pulp

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2021 14 (4)
Authors
Vigul, Dmitry O.; Tarabanko, Valery E.; Chelbina, Yulia V.; Levdansky, Vladimir A.
Contact information
Vigul, Dmitry O.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Scientific Center of the SB RAS» Krasnoyarsk, Russian Federation; Tarabanko, Valery E.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Scientific Center of the SB RAS» Krasnoyarsk, Russian Federation; ; Chelbina, Yulia V.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Scientific Center of the SB RAS» Krasnoyarsk, Russian Federation; Levdansky, Vladimir A.: Institute of Chemistry and Chemical Technology SB RAS FRC «Krasnoyarsk Scientific Center of the SB RAS» Krasnoyarsk, Russian Federation
Keywords
catalytic oxidation; cedar bark; pinus sibirica; lignin; vanillin; acetovanillone; vanillic acid; pulp; tannins
Abstract

The catalytic oxidation of natural and pre-extracted cedar bark (Pinus Sibirica) by molecular oxygen is studied. Tannins were shown to inhibit the formation of vanillin while oxidizing the bark. The yields of vanillin are 5–7 wt.% based on bark lignin, which is of 3–4 times lower compared to the results of wood oxidation. The presence of tannins in the raw material complicates the lignin analysis and can overestimate the results twice

Pages
457–463
DOI
10.17516/1998-2836-0254
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/145054