Journal of Siberian Federal University. Chemistry: New Carbonyl β-diketonate Rhodium (I) Complexes Containing 1-adamantyl Isocyanide

Journal of Siberian Federal University. Chemistry / New Carbonyl β-diketonate Rhodium (I) Complexes Containing 1-adamantyl Isocyanide

Issue

Journal of Siberian Federal University. Chemistry. 2022 15 (3)

Authors

Patrusheva, Anastasia A.; Chudin, Oleg S.; Verpekin, Victor V.; Nedelina, Tatyana S.; Kondrasenko, Alexander A.; Rubaylo, Anatoly I.

Contact information

Patrusheva, Anastasia A.: Intitute of Chemistry and Chemical Technology SB RAS Federal Research Centser ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Chudin, Oleg S.: Intitute of Chemistry and Chemical Technology SB RAS Federal Research Centser ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Verpekin, Victor V.: Intitute of Chemistry and Chemical Technology SB RAS Federal Research Centser ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; , ; Nedelina, Tatyana S.: Intitute of Chemistry and Chemical Technology SB RAS Federal Research Centser ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Kondrasenko, Alexander A.: Intitute of Chemistry and Chemical Technology SB RAS Federal Research Centser ‘‘Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation

Keywords

rhodium; isocyanide ligands; β-diketonate complexes; transition metals

Abstract

Синтезирована серия новых β-дикетонатных комплексов родия (I), содержащих 1-aдамантилизоцианидный лиганд (acac)Rh(CO)(CNAd) (1а), (dbm)Rh(CO)(CNAd) (2а) и (hfac) Rh(CO)(CNAd) (3а) (acac = ацетилацетонат, dbm = дибензоилметан, hfac= гексафторацетилацетон, Ad = 1-адамантил). Строение полученных соединений предложено на основании данных ИК- и ЯМР‑спектров. Исследованы реакции новых комплексов с диэтиламином

A series of new β-diketonate rhodium (I) complexes (acac)Rh(CO)(CNAd) (1а), (dbm)Rh(CO)(CNAd) (2а) and (hfac)Rh(CO)(CNAd) (3а) (acac = acetylacetonate, dbm = dibenzoyl methane, hfac = hexafluoroacetylacetonate, Ad = 1-adamantyl) containing adamantyl isocyanide ligand were synthesized. The new complexes were characterized by IR- and NMR‑spectroscopy. These spectroscopy data allow us to propose their molecular structures. The reactions between the new complexes and diethylamine were studied

Pages

431–439

DOI

10.17516/1998-2836-0306

Paper at repository of SibFU

https://elib.sfu-kras.ru/handle/2311/148514