Journal of Siberian Federal University. Chemistry / The Study of Dissolution Kinetics of the Phosphate Concentrate from Rivat Deposit

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2022 15 (4)
Authors
Qurbonov, Shodkom A.; Obidov, Behzod A.; Kholov, Kholmahmad I.; Samihov, Shonavruz R.
Contact information
Qurbonov, Shodkom A.: V.I. Nikitin Institute of Chemistry, National Academy of sciences of the Tajikistan Dushanbe, Republic of Tajikistan; ; Obidov, Behzod A.: Tajik National University of Tajikistan Dushanbe, Republic of Tajikistan; Kholov, Kholmahmad I.: V.I. Nikitin Institute of Chemistry, National Academy of sciences of the Tajikistan Dushanbe, Republic of Tajikistan; Samihov, Shonavruz R.: V.I. Nikitin Institute of Chemistry, National Academy of sciences of the Tajikistan Dushanbe, Republic of Tajikistan
Keywords
phosphate ore; phosphate concentrate; technical phosphoric acid; shrinking core model; dissolution rate; rate constant; activation energy
Abstract

Conducted kinetic study of dissolution of the concentrate obtained from the phosphate ore of the Rivat deposit in technical phosphoric acid. To determine the kinetics and their interaction mechanism, we studied certain parameters, such as the stirring speed (300, 500 and 700 rpm), the concentration of phosphoric anhydride (25, 30 and 35 % P2O5), as well as the temperature (60, 70 and 80 °C). It should be noted that the rate of dissolution of phosphorite concentrate increases with an increase of studied parameters. Due to the complexity of the dissolution of phosphates in mineral acids, this process has not fully explored. However, there are several different published materials on the kinetic model to describe this process, giving different expressions of the rate as a function of time. To study this process, the most suitable model is the shrinking core model. In this work, to calculate the rate constant k and the activation energy, we used solutions free of calcium sulfate

Pages
548–559
DOI
10.17516/1998-2836-0317
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/149786