Journal of Siberian Federal University. Chemistry / Thermodynamic Properties of Compounds Formed in SrO-Bi₂O₃, V₂O₅-Bi₂O₃ and PbO-Fe₂O₃ Systems

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2023 16 (3)
Authors
Denisova, Lyubov T.; Belousova, Natalia V.; Denisov, Viktor M.
Contact information
Denisova, Lyubov T.: Siberian Federal University Krasnoyarsk, Russian Federation; ; Belousova, Natalia V.: Siberian Federal University Krasnoyarsk, Russian Federation; Denisov, Viktor M.: Siberian Federal University Krasnoyarsk, Russian Federation
Keywords
thermodynamic properties; heat capacity; oxides of strontium, bismuth, lead, and iron
Abstract

A linear correlation has been established between the standard values of the enthalpies and the entropies of formation, the heat capacity , and the composition of oxide compounds formed in the SrO-Bi2O3, V2O5-Bi2O3, and PbO-Fe2O3 systems. The heat capacity of oxides of the SrO- Bi2O3 system was calculated using the Neumann-Kopp empirical relations, the Kumok incremental method, the Kellogg model and group contributions. It is found that the best agreement with the available experimental results is given by the Kumok method

Pages
417–425
EDN
JZWQPX
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/151718