Siberian Federal University 
- Supplementary material
- Application 1 (.pdf, 810 KB)
- Issue
- Journal of Siberian Federal University. Chemistry. 2024 17 (4)
- Authors
- Golubkov, Viktor A.; Zaitseva, Yulia N.; Sychev, Valentin V.; Eremina, Anna O.; Kirik, Sergei D.; Novikova, Svetlana A.; Litvintseva, Kseniya A.; Taran, Oxana P.
- Contact information
- Golubkov, Viktor A.: Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; ; Zaitseva, Yulia N.: Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Sychev, Valentin V. : Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Eremina, Anna O.: Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Kirik, Sergei D.: Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Novikova, Svetlana A. : Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Litvintseva, Kseniya A.: Federal Research Center “Boreskov Institute of Catalysis” SB RAS Novosibirsk, Russian Federation; Taran, Oxana P. : Institute of Chemistry and Chemical Technology SB RAS Federal Research Center “Krasnoyarsk Scientific Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Federal Research Center “Boreskov Institute of Catalysis” SB RAS Novosibirsk, Russian Federation
- Keywords
- SBA-15 silica; mesoporous; mesostructure; ruthenium; niobium oxide; xylose; hydrogenation; SBA-15
- Abstract
A novel Ru-catalysts based on niobia modified Zr-SBA-15 were developed for xylose to xylitol hydrogenation. The catalysts showed excellent activity and selectivity in the process at temperature as low as 70 °C providing 93 % conversion and >98 % selectivity within 90 min. As shown by the catalysts characterization: spectroscopy (XPS, UV–Vis DRS), microscopy (TEM), temperature-programmed reduction (TPR-H2) and low angle X-ray diffraction, niobium oxide has a strong interaction with the deposited ruthenium. This causes a slight decrease of the initial reaction rate of xylose hydrogenation. However, modification of Zr- SBA-15 with niobia drastically improves the acidic properties required for a potential use of the developed catalyst in one-pot hydrolysis-hydrogenation processing of plant polysaccharides into polyols, which will be the focus of a future research
- Pages
- 528–538
- EDN
- GKNMLS
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/154320
Journal of Siberian Federal University. Chemistry / Ruthenium Catalysts on Zr- SBA-15 and Nb/Zr- SBA-15 Supports for Xylose Hydrogenation
Full text (.pdf)