Journal of Siberian Federal University. Chemistry / Properties of Modified Petroleum Resins Based on Various Fractions of Liquid Pyrolysis Products

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2025 18 (1)
Authors
Bondaletov, Vladimir G.; Bondaletova, Liudmila I.; Nguyen Van Thanh; Bondaletova, Anna V.
Contact information
Bondaletov, Vladimir G.: National Research Tomsk Polytechnic University Tomsk, Russian Federation; Bondaletova, Liudmila I.: National Research Tomsk Polytechnic University Tomsk, Russian Federation; ; Nguyen Van Thanh: National Research Tomsk Polytechnic University Tomsk, Russian Federation; Bondaletova, Anna V. : National Research Tomsk Polytechnic University Tomsk, Russian Federation
Keywords
petroleum resin; fractions of liquid pyrolysis products; modification; nitration; reduction; coatings
Abstract

This article addresses the use of aliphatic, cycloaliphatic and aromatic petroleum resins obtained by radical (thermal and initiated) and ionic polymerization of unsaturated compounds of various fractions of liquid pyrolysis products as starting materials for modification by nitration with nitric acid and subsequent reduction with iron in the presence of hydrochloric acid. It has been established that nitration of petroleum resins leads to the appearance of nitro-, nitrate-, carbonyl and carboxyl groups in the polymer chain. Further modification of petroleum resins allows the introduction of amino groups into the composition of resins and significantly improves the performance characteristics of coatings based on the obtained resins: hardness, adhesion, and bending and impact strength

Pages
5–14
EDN
BPSTSW
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/155020