Journal of Siberian Federal University. Chemistry / In- Situ Transformation of High-Viscosity Oil in the Presence of Nickel Tallate Under Hydrothermal Conditions

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Supplementary material
Application 1 (.pdf, 2.6 MB)
Issue
Journal of Siberian Federal University. Chemistry. 2025 18 (1)
Authors
Mukhamatdinov, Irek I.; Abdrakhimova, Zalina T.; Mukhamatdinova, Rezeda E.; Vakhin, Aleksey V.
Contact information
Mukhamatdinov, Irek I. : Institute of Geology and Petroleum Technologies of Kazan Federal University Kazan, Russian Federation; ; Abdrakhimova, Zalina T. : Institute of Geology and Petroleum Technologies of Kazan Federal University Kazan, Russian Federation; Mukhamatdinova, Rezeda E. : Institute of Geology and Petroleum Technologies of Kazan Federal University Kazan, Russian Federation; Vakhin, Aleksey V.: Institute of Geology and Petroleum Technologies of Kazan Federal University Kazan, Russian Federation
Keywords
high viscosity oil; catalyst precursor; nickel tallate; resinous-asphaltene substances; catalytic activity; hydrothermal conditions; component composition; viscosity; SEM
Abstract

The study explored the composition and structure of transforming highly viscous oil under hydrothermal conditions, formed in situ from a nickel-based oil-soluble precursor. Notably, the catalyst significantly facilitates the breakdown of resins and asphaltenes. Specifically, experiments were conducted using oil-soluble nickel carboxylates and a hydrogen donor. Consequently, it was found that employing the catalyst precursor alters the gas composition of aquathermolysis products, rheological properties, and component composition. Moreover, when a nickel-based catalyst is utilized at 200 °C for 24 hours, the viscosity is reduced by 1.5 times compared to the control experiment. Additionally, the decomposition of the catalyst precursor results in the formation of nanometer- sized catalyst particles, as confirmed by scanning electron microscopy data. Thus, these particles do not clog the porous medium of the oil- saturated reservoir rock, allowing oil from other layers to be involved in the upgrading process

Pages
74–84
EDN
PBOCSB
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/155027