Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2025 18 (2)
- Authors
- Karachevsky, Daniil Yu.; Mustafin, Akhat G.
- Contact information
- Karachevsky, Daniil Yu. : RN-BashNIPIneft LLC (Company of Rosneft Group) Ufa, Russian Federation; Ufa Institute of Chemistry – a separate structural of the Ufa Federal Research Center RAS Ufa, Russian Federation; ; Mustafin, Akhat G.: RN-BashNIPIneft LLC (Company of Rosneft Group) Ufa, Russian Federation
- Keywords
- acetophenone oxime; Beckman rearrangement; acetanilide; n-methylbenzamide
- Abstract
The rearrangement of acetophenonoxime on the surface of iron sulfide has been studied, in which the mechanism of interaction of ketoximes with the metal surface has been established. As an example, the mechanism of interaction of acetophenonoxide with iron sulfide, which is the main corrosion product in the NACE+H2S environment, is considered. The study was conducted using solid- phase NMR (nuclear magnetic resonance). It was found that acetophenonoxime performs a Beckman rearrangement to the corresponding acetanilide and N-methylbenzaoamide (NMB). Additionally, the inhibitory properties of compounds obtained as a result of the rearrangement of acetophenone oxime were evaluated
- Pages
- 262–274
- EDN
- OIKBZW
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/156213
Journal of Siberian Federal University. Chemistry / The Mechanism of Interaction of Ketoximes with the Metal Surface. Beckman Rearrangement on the Surface of Iron Sulfide
Full text (.pdf)