Journal of Siberian Federal University. Chemistry / Solvation Dynamics and Physicochemical Properties of Potassium Chloride in Acetone-Water Solvent System

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2025 18 (3)
Authors
Anitha Vijayasundaram; Nishat Fatima; Sudha Ramani; Selvaraju Sivamani
Contact information
Anitha Vijayasundaram: College of Engineering and Technology, Engineering Department University of Technology and Applied Sciences Salalah, Oman; Nishat Fatima: College of Engineering and Technology, Engineering Department University of Technology and Applied Sciences Salalah, Oman; Sudha Ramani: College of Engineering and Technology, Engineering Department University of Technology and Applied Sciences Salalah, Oman; Selvaraju Sivamani: College of Engineering and Technology, Engineering Department University of Technology and Applied Sciences Salalah, Oman;
Keywords
potassium chloride; solubility; acetone-water solvent; physicochemical properties; solvation dynamics
Abstract

The study investigates the solvation dynamics and interactions of potassium chloride (KCl) in an acetone-water mixture by examining changes in density, viscosity, refractive index, and UV absorbance. As KCl is introduced into the mixed solvent system, notable changes in these physical properties are observed, revealing insights into the interplay between KCl ions and the acetone-water environment. The results indicate that increasing KCl concentration initially increases viscosity and refractive index due to ion-solvent interactions but also causes a gradual decrease in solution density. UV spectra reveal that water stabilizes KCl ions more effectively than acetone, resulting in higher UV absorbance in water-rich solutions. These findings underscore the role of solvent composition in governing solvation behaviour of KCl and provide a foundation for further exploration of electrolyte behaviour in mixed solvents, which is crucial for applications in analytical chemistry and materials science

Pages
343–354
EDN
IQJBWW
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/157139