Journal of Siberian Federal University. Chemistry / Investigation of Redox Properties of the System ''Water Solution-Tributilphosphate-Hypochlorous Acid''

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2009 2 (3)
Authors
Kuzmin, Dmitry V.; Kuzmin, Vladimir I.; Pashkov, Gennady L.
Contact information
Kuzmin, Dmitry V. : Institute of Chemistry and Chemical Technology SB RAS; 42 K. Marx, Krasnoyarsk, 660049 Russia, e-mail: ; Kuzmin, Vladimir I. : Institute of Chemistry and Chemical Technology SB RAS; 42 K. Marx, Krasnoyarsk, 660049 Russia,; Pashkov, Gennady L. : Institute of Chemistry and Chemical Technology SB RAS; 42 K. Marx, Krasnoyarsk, 660049 Russia,
Keywords
hypochlorous acid; extraction; TBP
Abstract

New heterogeneous oxidant - the system "TBP-HClO" was found during the investigation of the halogen extraction by TBP from the solutions of different composition. It can be used for providing redox reactions in hydrometallurgical processes, including the extraction of non-ferrous and rare metals. In this work redox properties of this reagent are considered.Organic solutions of hypochlorous acid in TBP are stable and they have high oxidative activity, that allows to recommend them for providing heterogeneous oxidation of water phase components.

Pages
241-245
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/1591