Journal of Siberian Federal University. Engineering & Technologies / Interaction of Rhodium with Chloro-Complexes of Palladium at Elevated Temperatures

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Issue
Journal of Siberian Federal University. Engineering & Technologies. 2015 8 (4)
Authors
Belousov, Oleg V.; Belousova, Natalya V.
Contact information
Belousov, Oleg V.:Institute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; E-mail: ov_bel@icct.ru; Belousova, Natalya V.:Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
autoclave technologies; rhodium; palladium; metal nanoparticles; substitutional solid solutions
Abstract

Powders of superfine rhodium with mono- and polyblock structures were obtained. The processes of coarsening of nanodispersed rhodium crystallites were investigated in detail at 130 and 180 °C. In muriatic solutions, dissolution of metal rhodium was found to occur. It was connected with the presence of chemisorbed oxygen at its surface. The possibility of formation of rhodium-palladium substitutional solid solutions on the electrolytic precipitation was firstly established

Pages
507-513
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/19663

Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0).

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