Journal of Siberian Federal University. Biology / Biosynthesis and Properties of PHA Containing Monomers 3-Hydroxy-4-Methylvalerate

Full text (.pdf)
Issue
Journal of Siberian Federal University. Biology. 2016 9 (2)
Authors
Vinogradova, Olga N.; Volova, Tatiana G.
Contact information
Vinogradova, Olga N.:Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Institute of Biophysics SB RAS 50/50 Akademgorodok, Krasnoyarsk, 660036, Russia; ; Volova, Tatiana G.:Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Institute of Biophysics SB RAS 50/50 Akademgorodok, Krasnoyarsk, 660036, Russia
Keywords
Cupriavidus eutrophus B10646; polyhydroxyalkanoates; poly(3-hydroxybutyrate/3-hydroxy-4-methylvalerate); Cupriavidus eutrophus B10646; substrates-precursors; 4-methylvalerate
Abstract

The ability of wild-type strain Cupriavidus eutrophus B10646 to synthesize copolymers containing 3-hydroxy-4-methylvalerate (3H4MV) [P(3HB/3HV/3H4MV)] was studied. The possibility of synthesis of terpolymers containing 3HB, 3HV and 3H4MV monomers using glucose, or butyric acid and co-substrate was shown. A family of copolymers with different content of 3H4MV monomer was synthesized. The highest content of 3H4MV was 7.7 mol. %. Increase of 3HV and 3H4MV content in copolymers caused the reduction of crystallinity degree and of molecular weight, and changes of thermal characteristics of copolymers

Pages
145-152
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/20360

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