Journal of Siberian Federal University. Chemistry / Prediction and Studied of the Phase Complex of NaF-NaI-Na2WO4 System

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2011 4 (3)
Authors
Ignatieva, Elena O.; Dvoryanova, Ekaterina M.; Garkushin, Ivan K.
Contact information
Ignatieva, Elena O. : Samara State Technical University General and Inorganic Chemistry Subdepartment , 244 Molodogvardeiskaya st., Samara, 443100 Russia; Dvoryanova, Ekaterina M. : Samara State Technical University General and Inorganic Chemistry Subdepartment , 244 Molodogvardeiskaya st., Samara, 443100 Russia; Garkushin, Ivan K. : Samara State Technical University General and Inorganic Chemistry Subdepartment , 244 Molodogvardeiskaya st., Samara, 443100 Russia , e-mail:
Keywords
the differential thermal analysis; phase equilibrium; eutectic
Abstract

Prediction of the phase complex of system NaF-NaI-Na2WO4 has been holded on the basis of phase equilibrium in the row of ternary systems NaF-NaHa -Na2WO4 (Hal - Cl, Br, I). We have methods for prediction characteristic of a ternary eutectic on basis of series exploration the single-type twocomponent and ternary system, comparative research its liquidus character, as well as building a series of dependencies. The three-component system NaF-NaI-Na2WO4 has been studied by the differential thermal analysis. As a result we have defined melting point temperature, and the compositions ternary eutectic mixture. We also have described the non and invariant equilibria.

Pages
276-284
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/2597