Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2011 4 (4)
- Authors
- Kenova, Tatyana A.; Vasilyeva, Irina S.; Kornienko, Vasiliy L.
- Contact information
- Kenova, Tatyana A. : Siberian Federal University Institute of Chemistry and Chemical Technology SB RAS , 79 Svobodny, Krasnoyarsk, 660041 Russia 42 K. Marx st., Krasnoyarsk, 660049Russia , e-mail: kta@icct.ru; Vasilyeva, Irina S. : Institute of Chemistry and Chemical Technology SB RAS , 42 K. Marx st., Krasnoyarsk, 660049Russia; Kornienko, Vasiliy L. : Institute of Chemistry and Chemical Technology SB RAS , 42 K. Marx st., Krasnoyarsk, 660049Russia
- Keywords
- PbO2 electrode; Pt electrode; electrochemical oxidation; thiocyanate-ion; cyanide-ion; active oxygen forms
- Abstract
The electrochemical oxidation of thicyanates on PbO2 and Pt electrodes under the high potential region has been investigated. It has been showed that the oxidation efficiency of thiocyanate-ion depends on electrolyze conditions ( pH of solution, the reagent concentration) and the electrode material. There is proposed the participation of active oxygen forms in the SCN− electrolytic oxidation besides his direct oxidation on the anode.
- Pages
- 384-392
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/2662
Journal of Siberian Federal University. Chemistry / Influence of Electrode Material and Electrolyze Conditions on the Electrochemical Oxidation of Thiocyanates
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