Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2011 4 (4)
- Authors
- Starkov, Alexander K.; Kozuchovskaya, Galina A.
- Contact information
- Starkov, Alexander K. : Institute of Chemistry and Chemical Technology , Siberian Branch of the Russian Academy of Sciences 42 K. Marx St., Krasnoyarsk, 660049 Russia; Kozuchovskaya, Galina A. : Institute of Chemistry and Chemical Technology , Siberian Branch of the Russian Academy of Sciences 42 K. Marx St., Krasnoyarsk, 660049 Russia , e-mail:
- Keywords
- complex compounds of platinum; synthesis; physicochemical properties; amines
- Abstract
Описаны новые способы синтеза и некоторые физико-химические свойства комплексов транс- дихлоро-бис-(амин)платины(II) с формулой транс-[PtA2Cl2], где А = метиламин, этиламин и изопропиламин, позволяющие повысить выход этих веществ. Изучена их растворимость в растворе 0,5 М KCl при 20 0С. Для доказательства индивидуальности, строения и характеристики физико-химических свойств комплексов использовали методы элементного анализа, РФА, ИКС, термогравиметрии, УФ-спектрофотометрии.
The new methods of synthesis and some physico-chemical properties of trans-dichlorobis-(amin) platinum(II) сomplexes with the formula trans-[PtA2Cl2], where A = methylamine, ethylamine, and isopropylamine were described. These methods allow to increase the yield and purity of substances. Their solubilites were studied at a temperature of 200C in a solution of 0.5 M KCl. To prove the identity, structure and characterization of physico-chemical properties of the complexes the methods of elemental analysis, XRD, IR, thermogravimetric analysis, UV-spectrophotometry were used.
- Pages
- 377-383
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/2667
Journal of Siberian Federal University. Chemistry / The Synthesis and Physico-chemical Studies of Complexes Trans-Dichloro-bis-(amin)platinum(II)
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