Journal of Siberian Federal University. Engineering & Technologies / About Some Properties and Features of Differential and Integrated Representations in the Theory of Thermodynamic Functions

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Issue
Journal of Siberian Federal University. Engineering & Technologies. 2016 9 (8)
Authors
Zhakatayev, Toksan A.; Sakipov, Kamalkhan E.; Kakimova, Klara Sh.
Contact information
Zhakatayev, Toksan A.: L.N. Gumilev Eurasian National University 13 K. Munitpasova Str., Astana, 010008, Kazakhstan; ; Sakipov, Kamalkhan E.: L.N. Gumilev Eurasian National University 13 K. Munitpasova Str., Astana, 010008, Kazakhstan; Kakimova, Klara Sh.: Karaganda State Technical University 56 Mira Boulevard Str., Karaganda, 100027, Kazakhstan
Keywords
thermodynamic function; pushing through work; thermodynamic potentials; enthalpy; law of energy conservation; moving volume of gas; mobile borders; final volume; final interval of change
Abstract

In article the comparative analysis of differential and integrated consideration of thermodynamic process is carried out. It is shown that use of the rule of replacement of variables of integration leads to correct output of main thermodynamic functions (an enthalpy, Helmholtz's function and Gibbs's function). It occurs through integrated consideration of thermodynamic process when parameters change in final (limited) intervals. It is established that Integrated consideration of the law of energy conservation in general view for the moving final volume of liquid or gas leads to «expanded» option of formula for the first law of thermodynamics. At the same time the equations recorded in differential form taking into account different types of technical work. Communications between the work of pushing through of some volume of gas and work connected with pressure at expansion of gas volume are shown

Pages
1314-1325
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/30354

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