Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2016 9 (3)
- Authors
- Kaygorodov, Konstantin L.; Parfenov, Vladimir A.; Ponomarenko, Ilya V.; Samoilo, Alexander S.
- Contact information
- Kaygorodov, Konstantin L.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; ; Parfenov, Vladimir A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Ponomarenko, Ilya V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Samoilo, Alexander S.: Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
- Keywords
- mesostructured silica materials; catalysis; acetalization; furfural; 5-hydroxymethylfurfural; methanol
- Abstract
Selective acetalization of furfural and 5-hydroxymethylfurfural by methanol in the presence of silica catalysts was investigated. Catalytic activity of silica materials (MCM-41, SBA-15, and silicagel) in reaction of furfural and 5-hydroxymethylfurfural acetalization by methanol was brought into correlation with its structure and textural properties. Mesostructured silica materials (MCM-41, SBA- 15) allow obtaining of furfural and 5-hydroxymethylfurfural methylacetals with the 80-95 % yield and up to 98 % selectivity
- Pages
- 267-280
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/30713
Journal of Siberian Federal University. Chemistry / The Use of Porous Silicate Materials with Different Structures for Acetalization of Furfural and 5-Hydroxymethylfurfural by Methanol
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