Journal of Siberian Federal University. Chemistry / Electrochemical Study of Cp(CO)₃MnRh(μ-C=CHPh)(acac) Complex

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2017 10 (2)
Authors
Burmakina, Galina V.; Verpekin, Victor V.; Zimonin, Dmitry V.; Chudin, Oleg S.; Nedelina, Tatyana S.; Rubaylo, Anatoly I.
Contact information
Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; , ; Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Nedelina, Tatyana S.: Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
electrochemistry; redox properties; binuclear complex; manganese; rhodium; carbonyl; vinylidene; acetylacetonate
Abstract

Redox properties of binuclear Cp(CO)₃ MnRh(μ-C=CHPh)(acac) complex were studied by electrochemical methods at platinum, glassed carbon and dropping mercury electrodes in acetonitrile. It was found that a reduction of the complex resulted in the formation of CpMn(CO)3 and rhodium Rh0 compounds whereas an oxidation gave CpMn(CO)3 and RhIII compounds

Pages
216-225
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/33639