Journal of Siberian Federal University. Chemistry / Phenylvinylidene Clusters Containing ReFePt Metal Cores and Chelate Diphosphine Ligands at the Platinum Atom

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Issue
Journal of Siberian Federal University. Chemistry. 2017 10 (2)
Authors
Verpekin, Victor V.; Kondrasenko, Alexander A.; Ergaev, Ruslan O.; Chudin, Oleg S.; Pavlenko, Nina I.; Rubaylo, Anatoly I.
Contact information
Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; ; Kondrasenko, Alexander A.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Ergaev, Ruslan O.: Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Pavlenko, Nina I.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
rhenium; platinum; iron; cluster; vinylidene; heterometallic complexes; vinylidene complexes
Abstract

Two different synthetic methods were applied to obtain heteronuclear phenylvinylidene clusters CpReFePt(μ3-C=CHPh)(CO)5(P-P) (P-P – bis(diphenylphosphino)ethane (1), bis(diphenylphosphino) propane (2)). The compounds were studied by IR and NMR spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data

Pages
239-249
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/33641