Journal of Siberian Federal University. Chemistry / Electrochemical Study of a Heterobinuclear pyridylvinylidene Complex Cp(CO)2Fe[μ-C=CH(2-C5H4N)]PdI

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2017 10 (3)
Authors
Verpekin, Victor V.; Burmakina, Galina V.; Zimonin, Dmitry V.; Pavlenko, Nina I.; Semeikin, Oleg. V.; Kreindlin, Arkadii Z.
Contact information
Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; ; ; Burmakina, Galina V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; Zimonin, Dmitry V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Pavlenko, Nina I.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Semeikin, Oleg. V.: A.N. Nesmeyanov Institute of Organoelement Compounds RAS 28 Vavilova Str., Moscow, 119991, Russia; Kreindlin, Arkadii Z.: A.N. Nesmeyanov Institute of Organoelement Compounds RAS 28 Vavilova Str., Moscow, 119991, Russia
Keywords
electrochemistry; redox properties; binuclearcomplexes; μ-pyridylvinylidene complexes; iron; palladium
Abstract

The redox properties of binuclear complex Cp(CO)2Fe[μ-C=CH(2-C5H4N)]PdI were studied by electrochemical methods at platinum, glassed carbon and dropping mercury electrodes in acetonitrile solution. It was found that a one-electron oxidation of the complex resulted in a cation-radical, which further undergoes decomposition, whereas a reduction gave an anion-radical, which further transforms into the 2-pirydylethynyl complex of iron Cp(CO)2Fe-C≡C-(2-C5H4N)

Pages
428-436
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/68948