Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2008 1 (1)
- Authors
- Chudin, Oleg S.; Antonova, Alla B.; Pavlenko, Nina I.; Sokolenko, William A.; Rubaylo, Anatoly I.; Vasiliev, Alexander D.; Semeikin, Oleg V.
- Contact information
- Oleg S. Chudin, Alla B. Antonova, Nina I. Pavlenko, William A. Sokolenko, Anatoly I. Rubaylo: Institute of Chemistry and Chemical Technology SB RAS,42 K. Marx st., Krasnoyarsk, 660049, Russia, e-mail: ; Anatoly I. Rubaylo: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041, Russia; Alexander D. Vasiliev: Institute of Physics, SB RAS, Akademgorodok, Krasnoyarsk, 660036, Russia; Oleg V. Semeikin: A.N. Nesmeyanov Institute of Organo-Element Compounds, Russian Academy of Sciences, Vavilov st., 28, Moscow, 117813, Russia
- Keywords
- Vinylidene complexes; Heterometallic complexes; Manganese; Rhenium; Platinum; R and NMR spectroscopy; Crystal structure
- Abstract
The interaction between Cp(CO)2Re=C=CHPh (1) and Pt(PPh3)4 afforded the μ-vinylidene complex Cp(CO)2RePt(μ-C=CHPh)(PPh3)2 (2). The IR and 1H, 13C and 31P NMR spectra of complex 2 were studied. Crystal and molecular structure of complex 2 has been determined by an X-ray single crystal analysis. The bond distances and angles are Re—Pt 2.7360(3), Re—C1 2.083(5), Pt—C1 2.008(4), C1=C2 1.351(6) Å; Pt-C1-C2 133.5(4), Re-C1-C2 141.6(4)°. The influence of the nature of the M = Re, Mn atoms on structural and spectroscopic characteristics of complexes Cp(CO)2MPt(μ-C=CHPh)-(PPh3)2 has been considered.
- Pages
- 60-70
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/701
Journal of Siberian Federal University. Chemistry / Chemistry of Vinylidene Complexes. XVII. The First μ-vinylidene Complex with the Re-Pt Bond: Synthesis, Spectroscopic Study and Structure of (η5-C5H5)(CO)2RePt(μ-C=CHPh)(PPh3)2
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