Journal of Siberian Federal University. Chemistry / The Product Produced by Interaction of the Cis-diammin(cyclobutane 1,1 dicarboxylato) Platinum(II) with Arabinogalactan

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Issue
Journal of Siberian Federal University. Chemistry. 2018 11 (2)
Authors
Starkov, Alexander K.; Kozuchovskaya, Galina A.; Pavlenko, Nina I.; Kirik, D.
Contact information
Starkov, Alexander K.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Kozuchovskaya, Galina A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; ; Pavlenko, Nina I.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Kirik, D.: Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
complex compound of platinum; synthesis; physic-chemical properties; arabinogalactan; amines; anticancer activity
Abstract

Получен продукт взаимодействия комплекса цис-диамин(циклобутан-1,1-дикарбоксилат- О,О`) платина(II) с арабиногалактаном, который охарактеризован методами РФА, рентгенофлуоресцентным, ИК-спектроскопии, термогравиметрии и УФ-спектрофотоментии, установлен его состав. Показано, что цис-диамин(циклобутан-1,1-дикарбоксилат-О,О`) платина(II) предположительно связан с арабиногалактаном водородными связями, образованными группами -С-О-С- и NH3-группами исходного комплекса

The obtained new product of reaction of the complex cis-diammin (cyclobutane 1,1 dicarboxylato) platinum(II) with arabinogalactan was characterized by XRD, IR-spectroscopy, UF-spectrophotometry and thermogravimetry. The composition and structure of this product was studied. It has been shown that cis-diammin(cyclobutane 1,1 dicarboxylato) platinum(II) associated with arabinogalactan through communications -C-О-C- groups by hydrogen of the original complex

Pages
211-218
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/71616