Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2012 5 (4)
- Authors
- Kositsyna, Anna S.; Root, Evgeniy V.; Gavrilova, Natalya A.; Semichenko, Elena S.; Suboch, George A.
- Contact information
- Kositsyna, Anna S.: Siberian State Technological University , 82 Mira, Krasnoyarsk, 660049 Russia , e-mail: ; Root, Evgeniy V.: Siberian State Technological University , 82 Mira, Krasnoyarsk, 660049 Russia; Gavrilova, Natalya A.: Siberian State Technological University , 82 Mira, Krasnoyarsk, 660049 Russia; Semichenko, Elena S.: Siberian State Technological University , 82 Mira, Krasnoyarsk, 660049 Russia; Suboch, George A.: Siberian State Technological University , 82 Mira, Krasnoyarsk, 660049 Russia
- Keywords
- 1; N; 3; 1; 4-phenylenediamine; 3; 5-substituted4-nitrosoaniline; cyclocondensation; 2-hydroxyimino 1; 3-diketone; reduction; cyclohexylamine; propan-2-amine; (1-adamantyl)methanamine
- Abstract
Восстановлением N,3,5-замещенных 4-нитрозоанилинов гидразингидратом на Pd/C получены N-3,5-замещенные 1,4-фенилендиамины. Синтез N-((1-адамантил)метил)-3,5-замещенных 4-нитрозоанилинов впервые осуществлен конденсацией 2-гидроксимино-1,3-дикетонов с ацетоном и (1- адамантил)метанамином в пиридине.
N,3,5-Substituted 1,4-phenylenediamines were obtained by reduction of N,3,5-substituted 4-nitosoanilines by hydrazinehydrate on the Pd/C. N-((1-Аdamatyl)methyl)-3,5-substituted 4-nitrosoanilines were first synthesized by condensation of 2-hydroxyimino-1,3-diketone with acetone and (1-adamatyl)methanamine in pyridine.
- Pages
- 405-410
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/9549
Journal of Siberian Federal University. Chemistry / Synthesis of N,3,5-Substituted 1,4-Phenylenediamines
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