Journal of Siberian Federal University. Chemistry / The Synthesis and Physico-Chemical Studies of Nonsymmetric Complexes Trans-Dichlorodiaminplatinum(II)

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2013 6 (2)
Authors
Starkov, Alexander K.; Kozuchovskaya, Galina A.
Contact information
Starkov, Alexander K.: Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42, K. Marx Str., Krasnoyarsk, 660049 Russia; e-mail: kaz@icct.ru; Kozuchovskaya, Galina A.: Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42, K. Marx Str., Krasnoyarsk, 660049 Russia;
Keywords
complex compounds of platinum; synthesis; physicochemical properties; amines
Abstract

The new methods of synthesis and some physico-chemical properties of nonsymmetric сomplexes trans-dichlorodiaminplatinum(II) with the formula trans-[PtLL`Cl 2 ], where L,L` = methylamine, ethylamine, and isopropylamine were described. These methods allow increasing the yield and purity of the substances. Their solubilites were studied at a temperature of 20° C in a solution of 0.5 M KCl. To prove the identity, structure and characterization of physico-chemical properties of the complexes the methods of elemental analysis, XRD, IR, thermogravimetric analysis, UV-spectrophotometry were used.

Описаны новые способы синтеза и некоторые физико-химические свойства несимметричных комплексов транс-дихлородиаминоплатины(II) с формулой транс-[PtLL`Cl 2 ], где L, L` = метиламин, этиламин и изопропиламин. При температуре 20 °С в растворе 0,5 М KCl изучена их растворимость. Для доказательства индивидуальности, строения и характеристики физико-химических свойств несимметричных комплексов использовали методы элементного анализа, РФА, ИКС, термогравиметрии, УФ-спектрофотометрии.

Pages
203-209
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/9825
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