Siberian Federal University 
- Issue
- Journal of Siberian Federal University. Chemistry. 2018 11 (3)
- Authors
- Kirik, Nadezhda P.; Anshits, Natalia N.; Rabchevskii, Evgenii V.; Solovyov, Leonid A.
- Contact information
- Kirik, Nadezhda P.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; kiriknp@icct. ru; Anshits, Natalia N.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Rabchevskii, Evgenii V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Solovyov, Leonid A.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia
- Keywords
- fly ash ferrospheres; HF-modification; oxidative coupling of methane
- Abstract
Catalytic properties in the reaction of oxidative coupling of methane (OCM) of HF-modified ferrospheres separated from combustion brown coal fly ash are investigated. It is established that the modification of ferrospheres results in a significant increase in the efficiency of C2-hydrocarbons formation at 750 °C, the yield increases by 1.5-2.0 times, the content of ethylene in the C2-products – up to 30 %, and at 850 °C – up to 65 %. It is suggested that the high efficiency of ethylene formation is associated with the formation of oxifluoride centers, which are deactivated at 850 °C and converted into oxide centers of deep oxidation
- Pages
- 347-360
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/107065
Journal of Siberian Federal University. Chemistry / The Activity of the HF-Modified Ferrospheres in Oxidative Coupling of Methane
Full text (.pdf)