Journal of Siberian Federal University. Chemistry / Syntheses and Physical-Chemical Properties of Phenylvinylidene Complexes with MnPt Core, Containing Diphenylphosphine Ligand at the Platinum Atom

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Issue
Journal of Siberian Federal University. Chemistry. 2018 11 (3)
Authors
Chudin, Oleg S.; Verpekin, Victor V.; Kondrasenko, Alexander A.; Pavlenko, Nina I.; Rubaylo, Anatoly I.
Contact information
Chudin, Oleg S.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia;; Verpekin, Victor V.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Kondrasenko, Alexander A.: Institute of chemistry and chemical technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Pavlenko, Nina I.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Rubaylo, Anatoly I.: Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
manganese; platinum; vivylidene; heterometallic complexes; vinylidene complexes; carbonyl ligand; diphenylphosphine
Abstract

A synthetic approach to the new heterobinuclear μ-phenylvinylidene complexes Cp(CO)2MnPt(μ- C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)3 (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR- and NMR-spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data

Pages
390-400
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/107069