Journal of Siberian Federal University. Chemistry / Synthesis and Physicochemical Study of Xanthan Butyl Ether

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2021 14 (2)
Authors
Kazachenko, Aleksandr S.; Fetisova, Olga Yu.; Antonov, Aleksandr V.; Bondarenko, Galina N.; Sychev, Valentine V.
Contact information
Kazachenko, Aleksandr S.: Institute of Chemistry and Chemical Technology FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; ; Fetisova, Olga Yu.: Institute of Chemistry and Chemical Technology FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Antonov, Aleksandr V.: .: Institute of Chemistry and Chemical Technology FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Bondarenko, Galina N.: Institute of Chemistry and Chemical Technology FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation; Sychev, Valentin V.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” Krasnoyarsk, Russian Federation;
Keywords
xanthan; butyl ethers; structure; xanthan butyl ether
Abstract

Xanthan is an important polysaccharide widely used in many industrial fields. It is produced by the bacteria Xanthomonascampestris. Chemical modification of xanthan can open up new horizons for its use. In this work, xanthan butyl ester was obtained for the first time by the interaction of xanthan and bromobutane using sodium hydroxide as a catalyst. The composition and structure of the obtained new xanthan derivative was studied by elemental analysis, IR spectroscopy, X-ray phase analysis, scanning electron microscopy and thermal analysis. The introduction of a butyl group into the xanthan molecule was proved by elemental analysis and IR spectroscopy by the appearance of corresponding bands. It was shown by X-ray phase analysis that xanthan butyl ether has a more X-ray amorphous structure in comparison with the original xanthan. It was shown by scanning electron microscopy that xanthan butyl ether powder consists of particles of a larger size and a layered structure in comparison with the original xanthan. It has been shown by thermal analysis that xanthan butyl ether is less thermostable than the starting xanthan

Pages
137–146
DOI
10.17516/1998-2836-0223
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/141325