- Issue
- Journal of Siberian Federal University. Chemistry. 2025 18 (4)
- Authors
- Ionin, Vladislav A.; Fufaeva, Mariya S.; Ovsyannikova, Varvara S.; Golubkov, Viktor A.; Malyar, Yuriy N.; Taran, Oxana P.
- Contact information
- Fufaeva, Mariya S. : Institute of Petroleum Chemistry SB RAS (IPC SB RAS) Tomsk, Russian Federation; ; Ovsyannikova, Varvara S. : Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences (IPC SB RAS) Tomsk, Russian Federation; Golubkov, Viktor A. : Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Scientific Center of the SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Malyar, Yuriy N.: Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Scientific Center of the SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Taran, Oxana P. : Boreskov Institute of Catalysis SB RAS Novosibirsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation
- Keywords
- spruce bark; pectins; cryogel; polyvinyl alcohol; starch; biodegradation; mechanical properties
- Abstract
A process for extracting Siberian spruce (Picea obovata) bark has been developed, enabling the sequential isolation of resinous, tannic, and pectin substances. The isolated pectin substances are characterized by a high uronic acid content (61.4 %), a broad molecular weight distribution (PDI = 4.3, Mw ~24100 g/mol), and a structure typical of pectins. The Introduction of pectins into PVA‑water cryogels does not significantly affect the mechanical properties or melting point of the materials. However, the incorporation of pectins into a three ‑component PVA‑starch‑water system leads to a decrease in the elastic modulus and melting point of the cryogel, which is explained by the formation of a weaker and more uniform spatial gel network. Biodegradation of the test materials revealed that even with a mass loss of more than 75 %, the cryogels retain their elastic structure
- Pages
- 567–579
- EDN
- BDXBKW
- Paper at repository of SibFU
- https://elib.sfu-kras.ru/handle/2311/157953
Journal of Siberian Federal University. Chemistry / The Impact of Siberian Spruce Bark Pectins on the Biodegradation and Mechanical Properties of Cryogels Based on Polyvinyl Alcohol and Starch
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