Journal of Siberian Federal University. Chemistry / The Impact of Siberian Spruce Bark Pectins on the Biodegradation and Mechanical Properties of Cryogels Based on Polyvinyl Alcohol and Starch

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2025 18 (4)
Authors
Ionin, Vladislav A.; Fufaeva, Mariya S.; Ovsyannikova, Varvara S.; Golubkov, Viktor A.; Malyar, Yuriy N.; Taran, Oxana P.
Contact information
Fufaeva, Mariya S. : Institute of Petroleum Chemistry SB RAS (IPC SB RAS) Tomsk, Russian Federation; ; Ovsyannikova, Varvara S. : Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences (IPC SB RAS) Tomsk, Russian Federation; Golubkov, Viktor A. : Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Scientific Center of the SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Malyar, Yuriy N.: Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Scientific Center of the SB RAS” Krasnoyarsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation; Taran, Oxana P. : Boreskov Institute of Catalysis SB RAS Novosibirsk, Russian Federation; Siberian Federal University Krasnoyarsk, Russian Federation
Keywords
spruce bark; pectins; cryogel; polyvinyl alcohol; starch; biodegradation; mechanical properties
Abstract

A process for extracting Siberian spruce (Picea obovata) bark has been developed, enabling the sequential isolation of resinous, tannic, and pectin substances. The isolated pectin substances are characterized by a high uronic acid content (61.4 %), a broad molecular weight distribution (PDI = 4.3, Mw ~24100 g/mol), and a structure typical of pectins. The Introduction of pectins into PVA‑water cryogels does not significantly affect the mechanical properties or melting point of the materials. However, the incorporation of pectins into a three ‑component PVA‑starch‑water system leads to a decrease in the elastic modulus and melting point of the cryogel, which is explained by the formation of a weaker and more uniform spatial gel network. Biodegradation of the test materials revealed that even with a mass loss of more than 75 %, the cryogels retain their elastic structure

Pages
567–579
EDN
BDXBKW
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/157953