Journal of Siberian Federal University. Chemistry / 1-Adamantanol Alkylation of 1,8- and 1,3- Dihydroxynaphthalenes

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2016 9 (1)
Authors
Peterson, Ivan V.; Svirskaya, Nadezhda M.; Kondrasenko, Alexander A.; Rubaylo, Anatoliy I.
Contact information
Peterson, Ivan V.:Institute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; E-mail: ; Svirskaya, Nadezhda M.:Institute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Kondrasenko, Alexander A.:Institute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Rubaylo, Anatoliy I.:Institute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Krasnoyarsk Scientific Centre SB RAS 50 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Keywords
alkylation; dihydroxynaphthalenes; adamantane
Abstract

При взаимодействии 1,8- и 1,3-дигидроксинафталинов с 1-адамантанолом в среде уксусной и фосфорной кислот образуются моноадамантильные производные. 1,8-Дигидроксинафталин при нагревании до 200 °С с 1-адамантанолом с присутствии каталитических количеств 1-бромадамантана образует триадамантилзамещенный продукт

The interaction of 1,8- and 1,3-dihydroxynaphthalenes with 1-adamantanol in acetic and phosphoric acids medium leads to formation monoadamantylated derivatives. Heating of 1,8-dihydroxynaphthalene at 200 °С with 1-adamantanol in presence of catalytic amounts of 1-bromoadamantane triadamantyl substituted product was obtained

Pages
134-139
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/20291