Journal of Siberian Federal University. Chemistry / Preparative Synthesis of Furfural Diethyl Acetal Through the Direct Interaction of the Alcohol and Aldehyde

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2016 9 (2)
Authors
Chernyak, Mikhail Yu.; Tarabanko, Valery E.
Contact information
Chernyak, Mikhail Yu.:Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Tarabanko, Valery E.: Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia; Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia; E-mail:
Keywords
furfural; furfural diethyl acetal; calcium oxide; diffusion; equilibrium; catalysis; biofuels
Abstract

A possibility of the furfural diethyl acetal preparation by direct interaction of the aldehyde and a slight excess of ethanol with high selectivity and preparative yield of 70 % was demonstrated. To shift the acetalization equilibrium the water vapour was absorbed by calcium oxide from gas phase. The acetalization process suggested is accelerated by the acid catalysts

Pages
146-151
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/26406